CASorganic LLC


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CASorganic LLC - Your partner in biochemical's industry


 

CasOrganic's US Corporation offers versitile biochemicals and fine chemicals, peptide reagents which include coupling reagents, N-protecting reagents and miscellaneous compounds that might be used in amide bond formation. In recent years, peptide coupling reactions have been significantly advanced in accord with the development of new peptide coupling reagents in organic synthesis. Research and development of new peptide coupling reagents has been steadily accelerated in the past few years. Moreover, tremendously expanded applications have been possible to new and broad synthetic challenges. Among many, coupling reagents responsible for the formation of azide, mixed anhydride, and acid halide intermediates have gained substantial popularity in peptide coupling reactions. DCC as a peptide-coupling reagent has particularly attracted organic chemists in their synthesis of complex molecules. Moreover, the development of onium-type coupling reagents has made the incorporation of non-coded or sterically hindered amino acids including N-methylated and a,a-dialkylated amino acids smoothly into the corresponding peptides possible.

 

Featured Products

 

Phosphonium reagents

Uronium reagents

Immonium reagents

Carbodiimide reagents

Imidazolium reagents

Organophosphorous reagents

Acid halogenating reagents

Chloroformate, pyridinium and other coupling reagents

Racemisation suppressants

 

Efficient coupling reagent for the preparation of various derivatives of acids [1,2,3,4,5,6,7,8,9].
Product Description
Product Name
CMPI
Structure
IUPAC Name, Synonims
CMPI
2-CHLORO-1-METHYLPYRIDINIUM IODIDE
2-CHLORO-N-METHYLPYRIDINIUM IODIDE
N-Methyl-2-chloropyridinium iodide~Mukaiyamas
N-Methyl-2-chloropyridiniumiodide
2-CHLORO-N-METHYLPYRIDINIUM IODIDE (CMPI)
Pyridinium, 2-chloro-1-methyl-, iodide
CMPI 2-CHLORO-1-METHYLPYRIDINIUM IODIDE
2-CHLORO-1-METHYLPYRIDINIUM IODIDE 97
CAS No
14338-32-0
Molecular Formula
C6H7NICl
Molecular Weight
255.49
Refractive index
Density
Appearance
Melting Point
200 °C
Purity
>98%
Loss on dryging
0.6%
Heavy metals
---
Packing
1kg; 25kg; 50kg
References
1. T. Mukaiyama Angew. Chem. 91, 798, (1979)
2. H.J. Koeners et al. Tetrahedron Lett. 21, 381, (1980)
3. K. Narasako et al. Chem. Lett. (Jpn), 455, (1982)
4. Y. Takikawa et al. Chem. Lett. (Jpn), 641, (1982)
5. H. Huang et al. Chem. Lett. (Jpn), 1465, (1984)
6. L. Strekowski et al. Synthesis, 493, (1983)
7. E. Kohl-Mines, H.-J. Hansen Helv. Chim. Acta 68, 2244, (1985)
8. N.J. Anthony et al. Tetrahedron Lett. 30, 3209, (1989)
9. T.K. Jones et al. J. Am. Chem. Soc. 111, 1157, (1989)